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p-Block Elements: Part I (Group 13 & 14) JEE Main PYQs, 2020 to 2025

p-Block Elements: Part I (Group 13 & 14) has 41 questions in JEE Main papers from 2020 to 2025, about 6.8 per year across all shifts. The most asked topic is Group 13: Boron Family (29 questions), followed by Group 14: Carbon Family (12).

Updated

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41Total PYQs
6Years covered
2Topics
2025 Apr S2Latest paper

p-Block Elements: Part I (Group 13 & 14) questions per year

YearQuestions
20256
202412
20239
20226
20217
20201

Topic-wise weightage

TopicQuestionsShare of chapterLast asked
Group 13: Boron Family2971%2025
Group 14: Carbon Family1229%2025

Sample questions from recent papers

JEE Main 2025 · 7 Apr · Shift 2 · Group 13: Boron Family

The correct statements from the following are :

(A) Tl3+ is a powerful oxidising agent

(B) Al3+ does not get reduced easily

(C) Both Al3+ and Tl3+ are very stable in solution

(D) Tl1+ is more stable than Tl3+

(E) Al3+ and Tl1+ are highly stable

Choose the correct answer from the options given below :

  1. (A)

    (A), (B), (D) and (E) only

  2. (B)

    (A), (C) and (D) only

  3. (C)

    (A), (B), (C) and (E)

  4. (D)

    (B), (D) and (E) only

Answer: (A)

Step-by-step solution

JEE Main 2025 · 7 Apr · Shift 1 · Group 14: Carbon Family

The group 14 elements AA and BB have the first ionisation enthalpy values of 708 and 715 kJ mol−1715 \mathrm{~kJ} \mathrm{~mol}^{-1} respectively. The above values are lowest among their group members. The nature of their ions A2+\mathrm{A}^{2+} and B4+\mathrm{B}^{4+} respectively is

  1. (A) both reducing
  2. (B) oxidising and reducing
  3. (C) both oxidising
  4. (D) reducing and oxidising

Answer: (D)

Step-by-step solution

All 41 questions are in the free PDF above, grouped by topic.

Frequently asked

How many questions come from p-Block Elements: Part I (Group 13 & 14) in JEE Main?

41 questions from 2020 to 2025, about 6.8 per year. In 2025 it had 6.

Which p-Block Elements: Part I (Group 13 & 14) topics are most important for JEE Main?

By past papers: Group 13: Boron Family (71%) and Group 14: Carbon Family (29%) of all p-Block Elements: Part I (Group 13 & 14) questions.

Is the p-Block Elements: Part I (Group 13 & 14) PYQ PDF free?

Yes. The PDF, the answer key and every step-by-step solution on PrepWiser are free, with no login needed to practise.

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