JEE Main 2025 · 8 April · evening · Single correct · +4 / −1

The correct decreasing order of spin only magnetic moment values (BM) of Cu⁺, Cu²⁺, Cr²⁺ and Cr³⁺ ions is :

  1. (a) Cr³⁺ > Cr²⁺ > Cu⁺ > Cu²⁺
  2. (b) Cu⁺ > Cu²⁺ > Cr³⁺ > Cr²⁺
  3. (c) Cr²⁺ > Cr³⁺ > Cu²⁺ > Cu⁺
  4. (d) Cu²⁺ > Cu⁺ > Cr²⁺ > Cr³⁺
Answer and solution

Answer (c) Cr²⁺ > Cr³⁺ > Cu²⁺ > Cu⁺

Solution

Chemistry ma’am · 2 steps

Write each ion's d-electron count, count the unpaired ones, and the order follows.

  1. Remove 4s first. Cr is [Ar] 3d⁵ 4s¹ and Cu is [Ar] 3d¹⁰ 4s¹. When these atoms form ions, the 4s electron leaves before any 3d electron.

    μ = √n(n+2) BM

    Iond configurationUnpaired electrons nμ (BM)
    Cr²⁺3d⁴4√24 = 4.90
    Cr³⁺3d³3√15 = 3.87
    Cu²⁺3d⁹1√3 = 1.73
    Cu⁺3d¹⁰00
  2. So. The order is Cr²⁺ > Cr³⁺ > Cu²⁺ > Cu⁺, which is option (c).

The idea to keep. Spin-only moment depends only on the number of unpaired electrons. Write the d configuration, count the singles, and the ion with more unpaired electrons always has the larger moment.

Answer from the NTA final answer key. Solution by PrepWiser.

Study d & f Block Elements

Asked about 170 times in JEE Main since 2020. This question is from 2025.