JEE Main 2024 · 5 April · morning · Single correct · +4 / −1

The metal that shows highest and maximum number of oxidation state is :

  1. (a) Co
  2. (b) Mn
  3. (c) Fe
  4. (d) Ti
Answer and solution

Answer (b) Mn

Solution

Chemistry ma’am · 3 steps

Count the 4s and 3d electrons the metal can give away: Mn has seven, more than anyone else here.

  1. Where states come from. In the 3d series, the 4s and 3d electrons are close in energy, so the metal can lose any number of them. The highest oxidation state usually equals the total of 4s and 3d electrons, up to manganese.
  2. Why Mn peaks. Mn is 3d⁵ 4s², so all seven electrons are unpaired or easy to remove, giving +7 as in KMnO₄. After Mn the d electrons start pairing, and fewer of them can be used in bonding.
    MetalConfigurationOxidation statesHighestHow many
    Ti3d² 4s²+2, +3, +4+43
    Mn3d⁵ 4s²+2, +3, +4, +5, +6, +7+76
    Fe3d⁶ 4s²+2, +3, +4, +5, +6+65
    Co3d⁷ 4s²+2, +3, +4+43
  3. So. Manganese wins on both counts: the highest state (+7) and the most states (six, from +2 to +7). The answer is (b).

The idea to keep. Across the 3d series, the number of oxidation states rises up to Mn (3d⁵ 4s²) and then falls, because paired d electrons are harder to use. Mn is the peak with +7.

Answer from the NTA final answer key. Solution by PrepWiser.

Study d & f Block Elements

Asked about 170 times in JEE Main since 2020. This question is from 2024.