JEE Main 2021 · 27 August · evening · Single correct · +4 / −1
Hydrolysis of sucrose gives :
- (a) α-D-(-)-Glucose and β-D-(-)-Fructose
- (b) α-D-(+)-Glucose and α-D-(-)-Fructose
- (c) α-D-(-)-Glucose and α-D-(+)-Fructose
- (d) α-D-(+)-Glucose and β-D-(-)-Fructose
Answer and solution
Answer (d) α-D-(+)-Glucose and β-D-(-)-Fructose
Solution
Chemistry ma’am · 3 steps
Sucrose is α-glucose joined to β-fructose; hydrolysis hands back exactly those two.
- Structure of sucrose. In sucrose, C1 of α-D-glucose is joined to C2 of β-D-fructose by a glycosidic bond. Breaking that bond with dilute acid or the enzyme invertase releases the two units.
- Sign of rotation. The (+) or (-) is the measured optical rotation, separate from D and from α or β. D-glucose is dextrorotatory (+52.5°) and D-fructose is laevorotatory (-92.4°). Because fructose rotates more strongly, the mixture turns left even though sucrose itself is (+). That is why the product is called invert sugar.
Option Glucose part Fructose part Verdict (a) α, but (-): wrong sign β, (-): correct wrong (b) α, (+): correct α: wrong anomer wrong (c) (-): wrong sign α, (+): wrong anomer and sign wrong (d) α, (+): correct β, (-): correct correct - So. Hydrolysis of sucrose gives α-D-(+)-glucose and β-D-(-)-fructose, option (d).
The idea to keep. Remember sucrose as α-glucose (C1) linked to β-fructose (C2). D tells you configuration and (+)/(-) tells you rotation: glucose is (+) and fructose is (-).
Answer from the NTA final answer key. Solution by PrepWiser.