JEE Main 2021 · 27 August · evening · Single correct · +4 / −1

Hydrolysis of sucrose gives :

  1. (a) α-D-(-)-Glucose and β-D-(-)-Fructose
  2. (b) α-D-(+)-Glucose and α-D-(-)-Fructose
  3. (c) α-D-(-)-Glucose and α-D-(+)-Fructose
  4. (d) α-D-(+)-Glucose and β-D-(-)-Fructose
Answer and solution

Answer (d) α-D-(+)-Glucose and β-D-(-)-Fructose

Solution

Chemistry ma’am · 3 steps

Sucrose is α-glucose joined to β-fructose; hydrolysis hands back exactly those two.

  1. Structure of sucrose. In sucrose, C1 of α-D-glucose is joined to C2 of β-D-fructose by a glycosidic bond. Breaking that bond with dilute acid or the enzyme invertase releases the two units.
  2. Sign of rotation. The (+) or (-) is the measured optical rotation, separate from D and from α or β. D-glucose is dextrorotatory (+52.5°) and D-fructose is laevorotatory (-92.4°). Because fructose rotates more strongly, the mixture turns left even though sucrose itself is (+). That is why the product is called invert sugar.
    OptionGlucose partFructose partVerdict
    (a)α, but (-): wrong signβ, (-): correctwrong
    (b)α, (+): correctα: wrong anomerwrong
    (c)(-): wrong signα, (+): wrong anomer and signwrong
    (d)α, (+): correctβ, (-): correctcorrect
  3. So. Hydrolysis of sucrose gives α-D-(+)-glucose and β-D-(-)-fructose, option (d).

The idea to keep. Remember sucrose as α-glucose (C1) linked to β-fructose (C2). D tells you configuration and (+)/(-) tells you rotation: glucose is (+) and fructose is (-).

Answer from the NTA final answer key. Solution by PrepWiser.

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Asked about 150 times in JEE Main since 2020. This question is from 2021.