JEE Main 2020 · 8 January · evening · Single correct · +4 / −1

Two monomers in maltose are :

  1. (a) α-D-glucose and α-D-galactose
  2. (b) α-D-glucose and α-D-Fructose
  3. (c) α-D-glucose and α-D-glucose
  4. (d) α-D-glucose and β-D-glucose
Answer and solution

Answer (c) α-D-glucose and α-D-glucose

Solution

Chemistry ma’am · 3 steps

Maltose comes from breaking down starch, and starch is built only from α-D-glucose, so both halves match.

  1. Where maltose comes from. The enzyme diastase breaks starch into maltose. Starch is a chain of α-D-glucose units only, so its two-unit piece can contain nothing but α-D-glucose.
  2. The linkage. C1 of one α-D-glucose joins C4 of the other through an oxygen bridge. This is an α(1→4) glycosidic bond. The second unit keeps a free anomeric carbon, so maltose is a reducing sugar.
    DisaccharideMonomer unitsLinkage
    Sucroseα-D-glucose + β-D-fructoseC1 (glucose) to C2 (fructose)
    Maltoseα-D-glucose + α-D-glucoseC1 to C4
    Lactoseβ-D-galactose + β-D-glucoseC1 (galactose) to C4 (glucose)
  3. So. Maltose is made of two α-D-glucose units, which is option (c).

The idea to keep. Learn the three disaccharides as a set: sucrose is glucose + fructose, lactose is galactose + glucose, maltose is glucose + glucose, all α.

Answer from the NTA final answer key. Solution by PrepWiser.

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Asked about 150 times in JEE Main since 2020. This question is from 2020.