JEE Main 2023 · 13 April · evening · Single correct · +4 / −1
Given below are two statements, one is labelled as Assertion A and the other is labelled as Reason R.
Assertion A : The diameter of colloidal particles in solution should not be much smaller than wavelength of light to show Tyndall effect.
Reason R : The light scatters in all directions when the size of particles is large enough.
In the light of the above statements, choose the correct answer from the options given below:
- (a) Both A and R are correct and R is the correct explanation of A
- (b) A is true but R is false
- (c) Both A and R are correct but R is NOT the correct explanation of A
- (d) A is false but R is true
Answer and solution
Answer (a) Both A and R are correct and R is the correct explanation of A
Solution
Chemistry ma’am · 4 steps
Tyndall effect is just scattering, and scattering needs particles big enough to catch the light.
- What Tyndall effect is. When a beam of light passes through a colloid, the dispersed particles scatter it sideways. That scattered light makes the path of the beam visible from the side.
- Check Assertion A. Scattering is noticeable only when the particle diameter is not much smaller than the wavelength of light (400 to 700 nm). Particles in a true solution are below about 1 nm, far too small, so a true solution shows no Tyndall effect. A is true.
- Check Reason R. Colloidal particles (1 to 1000 nm) are large enough to scatter light in all directions. R is true.
- So. R gives the very reason behind A: the size condition in A matters because only large enough particles scatter light in all directions. Both are true and R explains A, so the answer is (a).
The idea to keep. Tyndall effect needs two things: particles not much smaller than the wavelength of light, and a refractive index different from the medium. True solutions fail the size test, which is why they show no beam.
Answer from the NTA final answer key. Solution by PrepWiser.