JEE Main 2020 · 3 September · morning · Single correct · +4 / −1

Tyndall effect is observed when:

  1. (a) The diameter of dispersed particles is similar to the wavelenght of light used.
  2. (b) The diameter of dispersed particles is much smaller than the wavelength of light used.
  3. (c) The diameter of dispersed particles is much larger than the wavelength of light used.
  4. (d) The refractive index of dispersed phase is greater than that of the dispersion medium.
Answer and solution

Answer (a) The diameter of dispersed particles is similar to the wavelenght of light used.

Solution

Chemistry ma’am · 3 steps

Light scatters well only when the particle size is close to the light's wavelength. That is colloid territory.

  1. What Tyndall means. When a beam of light passes through a colloid, the dispersed particles scatter it sideways, so the path of the beam becomes visible. This bright path is called the Tyndall cone.
  2. Size decides scattering. A particle scatters light strongly when its size is close to the wavelength of that light. Visible light is about 400 to 700 nm, and colloidal particles are about 1 to 1000 nm, so the sizes overlap.
    MixtureParticle sizeCompared with wavelengthTyndall effect
    True solutionbelow 1 nmmuch smallerno, light passes through
    Colloid1 to 1000 nmsimilaryes, beam path glows
    Suspensionabove 1000 nmmuch largernot the colloidal effect, particles block light and settle
  3. So. The Tyndall effect is seen when the diameter of the dispersed particles is similar to the wavelength of the light used, which is option (a).

The idea to keep. Tyndall effect needs two things: particle size not much smaller than the wavelength of light, and a large difference in refractive index between the dispersed phase and the medium.

Answer from the NTA final answer key. Solution by PrepWiser.

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Asked about 80 times in JEE Main since 2020. This question is from 2020.