JEE Main 2023 · 31 January · morning · Single correct · +4 / −1

Nd²⁺ = __________

  1. (a) 4f⁴ 6s²
  2. (b) 4f³
  3. (c) 4f⁴
  4. (d) 4f² 6s²
Answer and solution

Answer (c) 4f⁴

Solution

Chemistry ma’am · 3 steps

Write neutral Nd first, then take both electrons from 6s, never from 4f.

  1. Neutral neodymium. Nd has Z = 60, which is 6 more than xenon. Its configuration is [Xe] 4f⁴ 6s², so it has 4 electrons in 4f and 2 in 6s.
  2. Remove outermost first. When a lanthanoid forms a cation, it loses the 6s electrons first. The 6s shell has the highest principal quantum number, so those electrons are the outermost and the easiest to remove.

    Nd [Xe] 4f⁴ 6s² → Nd²⁺ [Xe] 4f⁴ + 2e⁻

  3. So. Nd²⁺ is [Xe] 4f⁴. The 4f count stays at 4, which is option (c).

The idea to keep. For lanthanoid ions, empty the 6s shell first. Ln²⁺ keeps all the 4f electrons of the atom, and Ln³⁺ loses one more, from 4f.

Answer from the NTA final answer key. Solution by PrepWiser.

Study d & f Block Elements

Asked about 170 times in JEE Main since 2020. This question is from 2023.