JEE Main 2020 · 6 September · morning · Single correct · +4 / −1

The correct statement with respect to dinitrogen is :

  1. (a) N₂ is paramagnetic in nature
  2. (b) it can be used as an inert diluent for reactive chemicals
  3. (c) it can combine with dioxygen at 25ᵒC
  4. (d) liquid dinitrogen is not used in cryosurgery
Answer and solution

Answer (b) it can be used as an inert diluent for reactive chemicals

Solution

Chemistry ma’am · 2 steps

Everything about N₂ comes back to one strong triple bond, so test each option against it.

  1. The triple bond. In N≡N the bond enthalpy is about 946 kJ mol⁻¹, one of the strongest bonds known. That makes dinitrogen very unreactive at room temperature.
    OptionWhat is trueVerdict
    (a) paramagneticAll 10 valence electrons are paired, σ 1s² and so on up to σ 2p_z², bond order 3diamagnetic, false
    (b) inert diluentIts inertness lets it blanket or dilute reactive chemicals without reactingtrue
    (c) reacts with O₂ at 25 °CN₂ + O₂ ⇌ 2NO needs very high temperature, about 2000 K or an electric arcfalse
    (d) not used in cryosurgeryLiquid N₂ boils at 77 K and is used to freeze and destroy tissuefalse
  2. So. Only (b) is correct: dinitrogen is used as an inert diluent and as an inert atmosphere for reactive chemicals.

The idea to keep. Dinitrogen is inert because of its very strong triple bond, and it is diamagnetic because every electron is paired. Its uses, like inert atmospheres and liquid N₂ as a coolant, come from these two facts.

Answer from the NTA final answer key. Solution by PrepWiser.

Study p-Block Elements — Part II (Group 15-18)

Asked about 110 times in JEE Main since 2020. This question is from 2020.