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p-Block Elements: Part II (Group 15-18) JEE Main PYQs PDF, 2020–2026

p-Block Elements: Part II (Group 15-18) has 105 questions in JEE Main papers from 2020 to 2026, about 15 per year across all shifts. The free PDF has 103 of them, each with its answer. The most asked topic is Group 15: Nitrogen Family (60 questions), followed by Group 16: Oxygen Family (20) and Group 17: Halogens (20).

Asked in JEE Main
1052020–2026, all shifts
In this free PDF
103with answers
Asked in 2026
11Latest paper: 2026 Apr S2
Most asked topic
Group 15: Nitrogen Family60 Qs · 57% of the chapter
Difficulty mix
51% easy · 49% mediumof the questions in the PDF

Answer key includedNo loginPractise online

Source: official NTA JEE Main papers · Updated

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1 of this chapter's questions came back in a later paper (2021–2026). See the most repeated.

How often it's asked in JEE Main

p-Block Elements: Part II (Group 15-18) had about 0.5 questions per shift in recent JEE Main papers (2024–26). Its share has fallen since 2020–22. Most asked topic: Group 15: Nitrogen Family. About 11 questions in the 2026 papers. (Some topics were cut in 2024; see what changed.)

It came up in about 26 of the 2024–26 shifts in our bank. Question types in 2020–2026: about 90 MCQs and about 15 numerical.

How many questions from p-Block Elements: Part II (Group 15-18) in JEE Main, year by year

YearQuestionsPer shiftMCQNumerical
2026110.6110
202590.581
2024100.591
2023160.7124
2022271.2243
2021220.8175
2020100.691
2020–20261050.79015

Most asked p-Block Elements: Part II (Group 15-18) topics, 2020–2026

TopicQuestions
Group 15: Nitrogen Family60
Group 16: Oxygen Family20
Group 17: Halogens20
Group 18: Noble Gases5

Counted from PrepWiser's question bank of JEE Main papers, 2020–2026. Per shift = questions that year ÷ shifts in our bank. Updated .

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p-Block Elements: Part II (Group 15-18) questions per year

YearAskedIn PDF
20261111
202598
20241010
20231616
20222727
20212221
20201010

in the free PDF asked, not in the PDFThe PDF only has questions we can print in full with a checked answer, so it holds 103 of the 105 asked.

Topic-wise weightage by year

How many p-Block Elements: Part II (Group 15-18) questions each topic had in every JEE Main year (all shifts), counting every question asked, including ones not in the PDF. Darker cells mean more questions.

TopicAskedShare2026202520242023202220212020
Group 15: Nitrogen Family6057%852821106
Group 16: Oxygen Family2019%1351361
Group 17: Halogens2019%2124353
Group 18: Noble Gases55%··13·1·
All topics105100%1191016272210

Swipe the table sideways for older years.

Newest questions (2026)

All 11 JEE Main 2026 p-Block Elements: Part II (Group 15-18) questions in the free PDF, latest shift first.

  1. JEE Main 2026 · 8 Apr · Shift 2 · Group 15: Nitrogen Family

    Find the correct statements related to group 15 hydrides.

    A. Reducing nature increases from NH3{\mathrm{NH}}_{3} to BiH3{\mathrm{BiH}}_{3}

    B. Tendency to donate lone pair of electrons decreases from NH3{\mathrm{NH}}_{3} to BiH3{\mathrm{BiH}}_{3}

    C. The stability of hydrides decreases from NH3{\mathrm{NH}}_{3} to BiH3{\mathrm{BiH}}_{3}

    D. HEH bond angle decreases from NH3{\mathrm{NH}}_{3} to SbH3(E={\mathrm{SbH}}_{3}({\mathrm{E}}= Elements of group 15)

    Choose the correct answer from the options given below :

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  2. JEE Main 2026 · 6 Apr · Shift 2 · Group 15: Nitrogen Family

    Treatment of a gas ' XX ' with a freshly prepared ferrous sulphate solution gives a compound ' YY ' as a brown ring. The compounds X and Y are.

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  3. JEE Main 2026 · 5 Apr · Shift 2 · Group 15: Nitrogen Family

    Given below are two statements :

    Statement I: Aluminium upon reaction with NaOH forms [Al(OH)6]3−{[{\mathrm{Al}}({\mathrm{OH}})_{6}]}^{{3-}} ion.

    Statement II : The geometry of ICl4−,ClO3−{\mathrm{ICl}}_{4}^{{-}},{\mathrm{ClO}}_{3}^{{-}}and IBr2−{\mathrm{IBr}}_{2}^{{-}}is square planar, pyramidal and linear respectively.

    In the light of the above statements, choose the correct answer from the options given below :

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  4. JEE Main 2026 · 5 Apr · Shift 1 · Group 15: Nitrogen Family

    Correct statements from the following are:

    A. Nitrogen in oxidation states from +1 to +4 disproportionates in acid medium.

    B. Nitrogen has the ability to form dπ{\mathrm{d}}\pi - pπ{\mathrm{p}}\pi multiple bonds with itself and other elements with small size and high electronegativity.

    C. N-N single bond is stronger than P-P single bond.

    D. Nitrogen has highest density in its group due to small size.

    E. The maximum covalency of nitrogen is four since it has only four valence orbitals for bonding.

    Choose the correct answer from the options given below:

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  5. JEE Main 2026 · 4 Apr · Shift 1 · Group 15: Nitrogen Family

    A monoatomic anion (A ) has 45 neutrons and 36 electrons. Atomic mass, group in the periodic table and physical state at room temperature of the element (A) respectively are

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  6. JEE Main 2026 · 4 Apr · Shift 1 · Group 16: Oxygen Family

    Given below are two statements :

    Statement I : The covalency of oxygen is generally two but it can exceed upto four. The oxidation state of oxygen in SO2{\mathrm{SO}}_{2} is -2 and in OF2{\mathrm{OF}}_{2} it is +2 .

    Statement II : The anomalous behaviour of oxygen when compared to the other elements of group 16 is due to its small size and high electronegativity.

    In the light of the above statements, choose the correct answer from the options given below

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  7. JEE Main 2026 · 28 Jan · Shift 1 · Group 15: Nitrogen Family

    Regarding the hydrides of group 15 elements EH3(E=N,P,As,Sb){\mathrm{EH}}_{3}({\mathrm{E}}={\mathrm{N}},{\mathrm{P}},{\mathrm{As}},{\mathrm{Sb}}), select the correct statement from the following :

    A. The stability of hydrides decreases down the group.

    B. The basicity of hydrides decreases down the group.

    C. The reducing character increases down the group.

    D. The boiling point increases down the group.

    Choose the correct answer from the options given below :

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  8. JEE Main 2026 · 28 Jan · Shift 2 · Group 17: Halogens

    Given below are two statements :

    Statement I : The increasing order of boiling point of hydrogen halides is HCl < HBr < HI < HF.

    Statement II : The increasing order of melting point of hydrogen halides is HCl < HBr < HF < HI.

    In the light of the above statements, choose the correct answer from the options given below :

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  9. JEE Main 2026 · 22 Jan · Shift 1 · Group 15: Nitrogen Family

    A 'p'-block element (E)({\mathrm{E}}) and hydrogen form a binary cation (EHx)+{({\mathrm{EH}}_{{{\mathrm{x}}}})}^{{+}}, while EH3{\mathrm{EH}}_{3} on treatment with K2HgI4{\mathrm{K}}_{2}{\mathrm{HgI}}_{4} in alkaline medium gives a precipitate of basic mercury(II)amido-iodine. Given below are first ionisation enthalpy values (kJmol−1)\left({\mathrm{kJ}}{\mathrm{mol}}^{{-1}}\right) for first element each from group 13, 14, 15 and 16. Identify the correct first ionisation enthalpy value for element E.

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  10. JEE Main 2026 · 22 Jan · Shift 1 · Group 17: Halogens

    Given below are two statements :

    Statement I : The halogen that makes longest bond with hydrogen in HX, has the smallest covalent radius in its group.

    Statement II : A group 15 element's hydride EH3{\mathrm{EH}}_{3} has the lowest boiling point among corresponding hydrides of other group 15 elements. The maximum covalency of that element E is 4 .

    In the light of the above statements, choose the correct answer from the options given below

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  11. JEE Main 2026 · 22 Jan · Shift 2 · Group 15: Nitrogen Family

    Given below are two statements :

    Statement I : Elements ' XX ' and ' YY ' are the most and least electronegative elements, respectively among N,As,Sb{\mathrm{N}},{\mathrm{As}},{\mathrm{Sb}} and P . The nature of the oxides X2O3{\mathrm{X}}_{2}{\mathrm{O}}_{3} and Y2O3{\mathrm{Y}}_{2}{\mathrm{O}}_{3} is acidic and amphoteric, respectively.

    Statement II : BCl3{\mathrm{BCl}}_{3} is covalent in nature and gets hydrolysed in water. It produces [B(OH)4]−{[{\mathrm{B}}({\mathrm{OH}})_{4}]}^{{-}} and [B(H2O)6]3+{[{\mathrm{B}}{({\mathrm{H}}_{2}{\mathrm{O}})}_{6}]}^{{3+}} in aqueous medium.

    In the light of the above statements, choose the correct answer from the options given below :

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Practise the 2026 p-Block Elements: Part II (Group 15-18) questions online

Sample questions from recent papers

JEE Main 2025 · 8 Apr · Shift 2 · Group 16: Oxygen Family

Given below are two statements:

Statement I: H2Se is more acidic than H2Te

Statement II: H2Se has higher bond enthalpy for dissociation than H2Te

In the light of the above statements, choose the correct answer from the options given below:

  1. (A)

    Both Statement I and Statement II are true

  2. (B)

    Statement I is true but Statement II is false

  3. (C)

    Both Statement I and Statement II are false

  4. (D)

    Statement I is false but Statement II is true

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Answer: (D)

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JEE Main 2025 · 2 Apr · Shift 1 · Group 17: Halogens

The property/properties that show irregularity in first four elements of group-17 is/are

(A) Covalent radius

(B) Electron affinity

(C) Ionic radius

(D) First ionization energy

Choose the correct answer from the options given below :

  1. (A)A, B, C and D
  2. (B)A and C only
  3. (C)B only
  4. (D)B and D only
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Answer: (C)

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JEE Main 2024 · 31 Jan · Shift 1 · Group 18: Noble Gases

Give below are two statements:

Statement - I: Noble gases have very high boiling points.

Statement - II: Noble gases are monoatomic gases. They are held together by strong dispersion forces. Because of this they are liquefied at very low temperature. Hence, they have very high boiling points.

In the light of the above statements, choose the correct answer from the options given below:

  1. (A)Both Statement I and Statement II are false.
  2. (B)Statement I is true but Statement II is false.
  3. (C)Statement I is false but Statement II is true.
  4. (D)Both Statement I and Statement II are true.
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Answer: (A)

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Frequently asked

How many questions come from p-Block Elements: Part II (Group 15-18) in JEE Main?

105 questions from 2020 to 2026, about 15 per year. In 2026 it had 11. The free PDF has 103 of them.

Which p-Block Elements: Part II (Group 15-18) topics are most important for JEE Main?

By past papers: Group 15: Nitrogen Family (57%), Group 16: Oxygen Family (19%) and Group 17: Halogens (19%) of all p-Block Elements: Part II (Group 15-18) questions.

Is the p-Block Elements: Part II (Group 15-18) PYQ PDF free?

Yes. The PDF and its answer key are free, and you can practise the questions online with no login, with step-by-step solutions where available.

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