True or false · +4 / −1
Zn²⁺ salts are white while Cu²⁺ salts are blue.
Answer and solution
Answer: true
Solution
Chemistry ma’am · 3 steps
Check the d-electrons first: a full d¹⁰ shell has no room for a d-d jump, a d⁹ shell does.
- Where colour comes from. In a transition metal ion, ligands split the d orbitals into two sets of slightly different energy. An electron can absorb visible light and jump to the higher set, and we see the complementary colour.
Ion Configuration d-d transition possible? Colour Zn²⁺ [Ar] 3d¹⁰ No, every d orbital is full white (colourless) Cu²⁺ [Ar] 3d⁹ Yes, one d orbital is half-filled blue - Why each one. With 3d¹⁰, Zn²⁺ has no vacancy in the upper d set, so no visible light is absorbed. With 3d⁹, Cu²⁺ absorbs red-orange light, and hydrated salts like CuSO₄.5H₂O look blue.
- So. The statement is true: Zn²⁺ salts are white and Cu²⁺ salts are blue.
The idea to keep. Colour in transition metal ions needs a d-d jump, so it needs partly filled d orbitals. Ions with d⁰ or d¹⁰, like Sc³⁺, Zn²⁺ and Cu⁺, are colourless.
Answer from the NTA final answer key. Solution by PrepWiser.