JEE Main 2024 · 31 January · morning · Single correct · +4 / −1

Identify the factor from the following that does not affect electrolytic conductance of a solution.

  1. (a) The nature of solvent used.
  2. (b) The nature of the electrolyte added.
  3. (c) The nature of the electrode used.
  4. (d) Concentration of the electrolyte.
Answer and solution

Answer (c) The nature of the electrode used.

Solution

Chemistry ma’am · 2 steps

Conductance is about ions moving through the solution, so ask what controls the ions, not the metal plates.

  1. What carries current. In an electrolytic solution the current is carried by ions moving through the liquid. So anything that changes how many ions there are, or how fast they move, changes the conductance.
    FactorHow it acts on the ionsAffects conductance?
    Nature of solventA solvent with a higher dielectric constant separates ions better, and a less viscous one lets them move fasterYes
    Nature of electrolyteA strong electrolyte gives more ions than a weak one, and ion size and charge change their speedYes
    Nature of electrodeThe electrode only collects the current at the surface. It adds no ions and does not change how ions move in the solutionNo
    ConcentrationIt changes how many ions there are in a given volume and how strongly they pull on each otherYes
  2. So. The nature of the electrode does not affect electrolytic conductance, so the answer is (c).

The idea to keep. Electrolytic conductance depends on the ions: the electrolyte, the solvent, the concentration and the temperature. The electrodes are only the contacts that let current in and out.

Answer from the NTA final answer key. Solution by PrepWiser.

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Asked about 170 times in JEE Main since 2020. This question is from 2024.