JEE Main 2020 · 9 January · evening · Single correct · +4 / −1

Amongst the following, the form of water with the lowest ionic conductance at 298 K is :

  1. (a) saline water used for intravenous injection
  2. (b) sea water
  3. (c) distilled water
  4. (d) water from a well
Answer and solution

Answer (c) distilled water

Solution

Chemistry ma’am · 3 steps

Conductance comes from dissolved ions, so the water with the fewest ions conducts least.

  1. What carries current. In water, current is carried by ions moving through the liquid. More dissolved ions means higher conductance.
    Form of waterDissolved ionsConductance
    Saline for injectionabout 0.9% NaCl, so plenty of Na⁺ and Cl⁻high
    Sea waterabout 3.5% salts, the most ions herehighest
    Distilled wateralmost none, only H⁺ and OH⁻ from self-ionisation, each about 10⁻⁷ mol L⁻¹lowest
    Well waterdissolved minerals such as Ca²⁺, Mg²⁺, HCO₃⁻moderate
  2. Why distilled is lowest. Distillation leaves the dissolved salts behind. What remains are the very few ions from H₂O ⇌ H⁺ + OH⁻, far too few to carry much current.
  3. So. Distilled water has the lowest ionic conductance at 298 K, option (c).

The idea to keep. Pure water is a very poor conductor. Its conductance comes almost entirely from dissolved salts, so ranking waters by conductance means ranking them by how much salt they hold.

Answer from the NTA final answer key. Solution by PrepWiser.

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Asked about 170 times in JEE Main since 2020. This question is from 2020.