JEE Main 2020 · 5 September · evening · Single correct · +4 / −1
The variation of molar conductivity with concentration of an electrolyte (X) in aqueous solution is shown in the given figure.
The electrolyte X is :
- (a) HCl
- (b) CH₃COOH
- (c) NaCl
- (d) KNO₃
Answer and solution
Answer (b) CH₃COOH
Solution
Chemistry ma’am · 3 steps
Look at the shape: a curve that shoots up only near zero concentration belongs to a weak electrolyte.
- Strong electrolytes. A strong electrolyte is almost fully ionised at every concentration. Its molar conductivity falls only slightly as √c grows, giving a nearly straight line, Λₘ = Λₘ° - A√c.
- Weak electrolytes. A weak electrolyte ionises only a little, and its degree of dissociation rises sharply on dilution. So Λₘ stays low over most of the range, then rises steeply as c approaches zero. That is the curve in the figure.
Electrolyte Type Λₘ vs √c HCl strong acid nearly straight line CH₃COOH weak acid steep rise only near c = 0 NaCl strong salt nearly straight line KNO₃ strong salt nearly straight line - So. The graph matches a weak electrolyte, so X is acetic acid, CH₃COOH, option (b).
The idea to keep. In a Λₘ vs √c plot, a gentle straight line means a strong electrolyte. A steep climb near zero concentration means a weak one, whose Λₘ° cannot be found by extrapolation.
Answer from the NTA final answer key. Solution by PrepWiser.