JEE Main 2020 · 5 September · evening · Single correct · +4 / −1

The variation of molar conductivity with concentration of an electrolyte (X) in aqueous solution is shown in the given figure.
The electrolyte X is :

JEE Main PYQ figure
  1. (a) HCl
  2. (b) CH₃COOH
  3. (c) NaCl
  4. (d) KNO₃
Answer and solution

Answer (b) CH₃COOH

Solution

Chemistry ma’am · 3 steps

Look at the shape: a curve that shoots up only near zero concentration belongs to a weak electrolyte.

  1. Strong electrolytes. A strong electrolyte is almost fully ionised at every concentration. Its molar conductivity falls only slightly as √c grows, giving a nearly straight line, Λₘ = Λₘ° - A√c.
  2. Weak electrolytes. A weak electrolyte ionises only a little, and its degree of dissociation rises sharply on dilution. So Λₘ stays low over most of the range, then rises steeply as c approaches zero. That is the curve in the figure.
    ElectrolyteTypeΛₘ vs √c
    HClstrong acidnearly straight line
    CH₃COOHweak acidsteep rise only near c = 0
    NaClstrong saltnearly straight line
    KNO₃strong saltnearly straight line
  3. So. The graph matches a weak electrolyte, so X is acetic acid, CH₃COOH, option (b).

The idea to keep. In a Λₘ vs √c plot, a gentle straight line means a strong electrolyte. A steep climb near zero concentration means a weak one, whose Λₘ° cannot be found by extrapolation.

Answer from the NTA final answer key. Solution by PrepWiser.

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Asked about 170 times in JEE Main since 2020. This question is from 2020.