JEE Main 2023 · 25 January · morning · Numerical answer · +4 / −0
The density of a monobasic strong acid (Molar mass 24.2 g/mol) is 1.21 kg/L. The volume of its solution required for the complete neutralization of 25 mL of 0.24 M NaOH is __________ × 10⁻² mL (Nearest integer)
Answer and solution
Answer 12
Solution
Chemistry ma’am · 4 steps
Use the density to find how many moles of acid sit in one litre, then match moles of acid to NaOH.
- Molarity from density. The density is 1.21 kg L⁻¹ = 1210 g L⁻¹, so one litre of the acid holds 1210 g of it. Divide by the molar mass to get the moles in that litre.
M_(acid) = (1210 g L⁻¹)/(24.2 g mol⁻¹) = 50 mol L⁻¹
- Moles of NaOH. 25 mL × 0.24 M = 6 mmol of NaOH. A monobasic acid gives one H⁺ per molecule, so you need exactly 6 mmol of acid.
- Volume of acid. V = (6 mmol)/(50 mmol mL⁻¹) = 0.12 mL.
- So. 0.12 mL = 12 × 10⁻² mL, so the answer is 12.
The common slip: 12000. Reading 1.21 kg/L as 1.21 g/L makes the acid 0.05 M and the volume 120 mL, which gives 12000 in units of 10⁻² mL.
The idea to keep. For a pure liquid, molarity is density in g/L divided by molar mass. For neutralisation, match the moles of H⁺ to the moles of OH⁻, and remember that mL times M gives mmol.
Answer from the NTA final answer key. Solution by PrepWiser.