JEE Main 2021 · 31 August · evening · Numerical answer · +4 / −0

Sodium oxide reacts with water to produce sodium hydroxide. 20.0 g of sodium oxide is dissolved in 500 mL of water. Neglecting the change in volume, the concentration of the resulting NaOH solution is ______________ × 10⁻¹ M. (Nearest integer) [Atomic mass : Na = 23.0, O = 16.0, H = 1.0]

Answer and solution

Answer 13

Solution

Chemistry ma’am · 4 steps

One Na₂O gives two NaOH, so double the moles before you divide by the volume.

  1. Balanced equation. Na₂O + H₂O → 2NaOH. Each mole of sodium oxide gives 2 moles of sodium hydroxide.
  2. Moles of Na2O. Molar mass of Na₂O = 2 × 23.0 + 16.0 = 62.0 g mol⁻¹. So 20.0 g is 20.0/62.0 = 0.3226 mol.
  3. Moles of NaOH. Moles of NaOH = 2 × 0.3226 = 0.6452 mol. The volume stays 500 mL = 0.500 L.

    M = (0.6452 mol)/(0.500 L) = 1.29 M = 12.9 × 10⁻¹ M

  4. So. The concentration is 12.9 × 10⁻¹ M, which rounds to 13.

The common slip: 6. Forgetting that one Na₂O gives two NaOH gives 0.645 M, that is 6, not 13.

The idea to keep. Always go through the balanced equation: convert grams of what you have into moles of what you want, then divide by litres of solution.

Answer from the NTA final answer key. Solution by PrepWiser.

Study Mole Concept & Stoichiometry

Asked about 210 times in JEE Main since 2020. This question is from 2021.