JEE Main 2024 · 27 January · evening · Single correct · +4 / −1
The order of relative stability of the contributing structure is :
Choose the correct answer from the options given below :
- (a) I = II = III
- (b) I > II > III
- (c) III > II > I
- (d) II > I > III
Answer and solution
Answer (b) I > II > III
Solution
Chemistry ma’am · 3 steps
Rank resonance structures by charges: none is best, then charges that suit electronegativity.
- Ranking rules. A neutral structure with full octets contributes most. If charges must appear, the structure is better when the negative charge sits on the more electronegative atom. It is worst when a highly electronegative atom carries a positive charge with an incomplete octet.
Structure Charges Octets Verdict I none all atoms complete most stable II + on C, - on O terminal C has only 6 charge separation, but - is on the electronegative O III - on C, + on O O has only 6 least stable: + on the electronegative atom, and it lacks an octet - Compare II and III. Both separate charge across the same atoms. Oxygen is more electronegative than carbon, so it carries the negative charge well in II. Forcing a positive charge and a sextet onto oxygen in III makes it the poorest contributor.
- So. The order of stability is I > II > III, which is option (b).
The idea to keep. To rank resonance structures, ask in order: full octets? fewest charges? negative charge on the more electronegative atom? Positive charge on oxygen with a sextet is almost always the worst.
Answer from the NTA final answer key. Solution by PrepWiser.