JEE Main 2026 · 28 January · evening · Single correct · +4 / −1

The cyclic cations having the same number of hyperconjugation are :
Choose the correct answer from the options given below :

JEE Main PYQ figure
  1. (a) B and C Only
  2. (b) A and B Only
  3. (c) A and C Only
  4. (d) A, C and D only
Answer and solution

Answer (c) A and C Only

Solution

Chemistry ma’am · 3 steps

Count the C–H bonds on carbons touching C⁺; each one gives a hyperconjugative structure.

  1. What to count. Each C–H bond on a carbon directly bonded to the positive carbon (an α-hydrogen) can overlap with its empty p orbital. So the number of hyperconjugative structures equals the number of α-hydrogens.
  2. Where to look. In every cation, C⁺ has three neighbours: the substituent it carries and the two ring carbons beside it. A ring CH₂ gives 2 α-H, but a ring carbon carrying an ethyl group is a CH and gives only 1.
    CationGroup on C⁺Two ring neighboursTotal α-H
    ACH₃: 3CH (has ethyl): 1, CH₂: 26
    BCH₃: 3CH₂: 2, CH₂: 27
    CCH₂CH₃: 2CH₂: 2, CH₂: 26
    DCH₂CH₃: 2CH (has ethyl): 1, CH₂: 25
  3. So. A and C both have 6 α-hydrogens, so they have the same number of hyperconjugative structures. B has 7 and D has 5, so the answer is (c).

The idea to keep. Hyperconjugation counts α-hydrogens only: look at every carbon bonded to C⁺. In an ethyl group only the CH₂ counts, and a ring carbon with a substituent has lost one H.

Answer from the NTA final answer key. Solution by PrepWiser.

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Asked about 180 times in JEE Main since 2020. This question is from 2026.