JEE Main 2021 · 18 March · evening · Single correct · +4 / −1

In the following molecule,
Hybridisation of Carbon a, b, and c respectively are :

JEE Main PYQ figure
  1. (a) sp³, sp², sp²
  2. (b) sp³, sp, sp²
  3. (c) sp³, sp², sp
  4. (d) sp³, sp, sp
Answer and solution

Answer (a) sp³, sp², sp²

Solution

Chemistry ma’am · 3 steps

Count the σ bonds on each labelled carbon: 4 means sp³, 3 means sp², 2 means sp.

  1. The counting rule. For a carbon, hybridisation follows the number of atoms it is bonded to. Four σ bonds gives sp³, three σ bonds plus one π bond gives sp², and two σ bonds plus two π bonds gives sp.
    CarbonBonded toσ bondsπ bondsHybridisation
    a (CH₃)3 H and 1 C40sp³
    b (alkene C)1 C, 1 H, 1 O31 (the C=C)sp²
    c (ring C)1 O and 2 ring C31 (in the ring)sp²
  2. Ignore the oxygen. The oxygen next to b and c only supplies one σ bond to each. Its lone pairs may be in resonance with the double bond and the ring, but resonance does not change the carbon's hybridisation.
  3. So. Carbons a, b and c are sp³, sp² and sp², which is option (a).

The idea to keep. For any carbon, just count its neighbours: 4 neighbours is sp³, 3 is sp², 2 is sp. Every benzene ring carbon is sp², whatever group sits on it.

Answer from the NTA final answer key. Solution by PrepWiser.

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Asked about 180 times in JEE Main since 2020. This question is from 2021.