JEE Main 2022 · 25 July · morning · Single correct · +4 / −1

The IUPAC nomenclature of an element with electronic configuration [Rn] 5 f¹⁴ 6 d¹ 7 s² is :

  1. (a) Unnilbium
  2. (b) Unnilunium
  3. (c) Unnilquadium
  4. (d) Unniltrium
Answer and solution

Answer (d) Unniltrium

Solution

Chemistry ma’am · 3 steps

Turn the configuration into an atomic number first, then spell that number digit by digit.

  1. Count the electrons. The core [Rn] holds 86 electrons. Add the ones written after it: 14 + 1 + 2 = 17. So Z = 86 + 17 = 103.
  2. Digit roots. IUPAC gives each digit a root: 0 = nil, 1 = un, 2 = bi, 3 = tri, 4 = quad. Write one root per digit, then add the ending -ium.
    OptionDigitsAtomic number
    (a) Unnilbiumun + nil + bi102
    (b) Unniluniumun + nil + un101
    (c) Unnilquadiumun + nil + quad104
    (d) Unniltriumun + nil + tri103
  3. So. Element 103, which is lawrencium, has the IUPAC name Unniltrium, option (d).

The idea to keep. For any heavy element, add the noble-gas core to the electrons written after it to get Z. Then read Z digit by digit: nil, un, bi, tri, quad, pent, hex, sept, oct, enn, and add -ium.

Answer from the NTA final answer key. Solution by PrepWiser.

Study Periodic Table & Periodicity

Asked about 120 times in JEE Main since 2020. This question is from 2022.