JEE Main 2020 · 2 September · evening · Single correct · +4 / −1
Three elements X, Y and Z are in the 3ʳᵈ period of the periodic table. The oxides of X, Y and Z, respectively, are basic, amphoteric and acidic. The correct order of the atomic numbers of X, Y and Z is :
- (a) X < Z < Y
- (b) Y < X < Z
- (c) Z < Y < X
- (d) X < Y < Z
Answer and solution
Answer (d) X < Y < Z
Solution
Chemistry ma’am · 3 steps
Across period 3, oxides go from basic to amphoteric to acidic, so the order of oxide nature is the order of Z.
- Trend across period. Moving left to right in period 3, atomic number rises and metallic character falls. Metal oxides are basic, non-metal oxides are acidic, and the ones in between are amphoteric.
Element Atomic number Oxide Nature Na 11 Na₂O basic Mg 12 MgO basic Al 13 Al₂O₃ amphoteric Si 14 SiO₂ weakly acidic P, S, Cl 15, 16, 17 P₄O₁₀, SO₃, Cl₂O₇ acidic, getting stronger - Place X, Y, Z. X has a basic oxide, so it is Na or Mg, before Al. Y has an amphoteric oxide, so Y is Al. Z has an acidic oxide, so it lies after Al, among Si to Cl.
- So. The atomic numbers increase as X < Y < Z, which is option (d).
The idea to keep. In any period, oxides turn from basic to amphoteric to acidic as you go left to right. Read the oxide's nature and you know where the element sits.
Answer from the NTA final answer key. Solution by PrepWiser.