JEE Main 2020 · 2 September · evening · Single correct · +4 / −1

Three elements X, Y and Z are in the 3ʳᵈ period of the periodic table. The oxides of X, Y and Z, respectively, are basic, amphoteric and acidic. The correct order of the atomic numbers of X, Y and Z is :

  1. (a) X < Z < Y
  2. (b) Y < X < Z
  3. (c) Z < Y < X
  4. (d) X < Y < Z
Answer and solution

Answer (d) X < Y < Z

Solution

Chemistry ma’am · 3 steps

Across period 3, oxides go from basic to amphoteric to acidic, so the order of oxide nature is the order of Z.

  1. Trend across period. Moving left to right in period 3, atomic number rises and metallic character falls. Metal oxides are basic, non-metal oxides are acidic, and the ones in between are amphoteric.
    ElementAtomic numberOxideNature
    Na11Na₂Obasic
    Mg12MgObasic
    Al13Al₂O₃amphoteric
    Si14SiO₂weakly acidic
    P, S, Cl15, 16, 17P₄O₁₀, SO₃, Cl₂O₇acidic, getting stronger
  2. Place X, Y, Z. X has a basic oxide, so it is Na or Mg, before Al. Y has an amphoteric oxide, so Y is Al. Z has an acidic oxide, so it lies after Al, among Si to Cl.
  3. So. The atomic numbers increase as X < Y < Z, which is option (d).

The idea to keep. In any period, oxides turn from basic to amphoteric to acidic as you go left to right. Read the oxide's nature and you know where the element sits.

Answer from the NTA final answer key. Solution by PrepWiser.

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Asked about 120 times in JEE Main since 2020. This question is from 2020.