JEE Main 2021 · 16 March · evening · Single correct · +4 / −1

The characteristics of elements X, Y and Z with atomic numbers, respectively, 33, 53 and 83 are :

  1. (a) X and Y are metalloids and Z is a metal.
  2. (b) X and Z are non-metals and Y is a metalloid.
  3. (c) X is a metalloid, Y is a non-metal and Z is a metal.
  4. (d) X, Y and Z are metals.
Answer and solution

Answer (c) X is a metalloid, Y is a non-metal and Z is a metal.

Solution

Chemistry ma’am · 3 steps

Place each atomic number in the periodic table first. Its group and period tell you the character.

  1. Locate each element. Use the outer electronic configuration to find the period and group. Then read where the element sits relative to the metalloid staircase running from B to At.
    ElementOuter configurationPositionCharacter
    X, Z = 33 (As)4s² 4p³Period 4, group 15metalloid
    Y, Z = 53 (I)5s² 5p⁵Period 5, group 17non-metal (halogen)
    Z, Z = 83 (Bi)6s² 6p³Period 6, group 15metal
  2. Trend down group 15. Metallic character rises down a group as atoms get larger and lose electrons more easily. Group 15 goes N, P (non-metals), As, Sb (metalloids), Bi (metal), so As and Bi land on opposite sides.
  3. So. X is a metalloid, Y is a non-metal and Z is a metal, which is option (c).

The idea to keep. For any atomic number, first find its group and period. In the p-block, character moves from non-metal to metalloid to metal as you go down a group or to the left.

Answer from the NTA final answer key. Solution by PrepWiser.

Study Periodic Table & Periodicity

Asked about 120 times in JEE Main since 2020. This question is from 2021.