JEE Main 2020 · 8 January · evening · Single correct · +4 / −1

The increasing order of the atomic radii of the following elements is :-
(a) C (b) O
(c) F (d) Cl
(e) Br

  1. (a) (a) < (b) < (c) < (d) < (e)
  2. (b) (c) < (b) < (a) < (d) < (e)
  3. (c) (b) < (c) < (d) < (a) < (e)
  4. (d) (d) < (c) < (b) < (a) < (e)
Answer and solution

Answer (b) (c) < (b) < (a) < (d) < (e)

Solution

Chemistry ma’am · 4 steps

Sort by period first, since a new shell wins; then within period 2, more nuclear charge means smaller.

  1. Across a period. C, O and F are all in period 2. Moving right, the nuclear charge rises but no new shell is added, so the electrons are pulled in closer. The radius therefore shrinks: F < O < C.
  2. Down a group. F, Cl and Br are in group 17. Each step down adds a whole new shell, so the radius grows: F < Cl < Br.
  3. Join the two. Even the largest period 2 atom (C) is smaller than the smallest period 3 atom here (Cl). The extra shell matters more than the change in nuclear charge.
    ElementPeriodGroupAtomic radius
    F21764 pm
    O21666 pm
    C21477 pm
    Cl31799 pm
    Br417114 pm
  4. So. The increasing order is F < O < C < Cl < Br, which is (c) < (b) < (a) < (d) < (e). That is option (b).

The idea to keep. For atomic size, a new shell beats everything else. Group by period first, then order within a period by nuclear charge: further right means smaller.

Answer from the NTA final answer key. Solution by PrepWiser.

Study Periodic Table & Periodicity

Asked about 120 times in JEE Main since 2020. This question is from 2020.