JEE Main 2024 · 1 February · morning · Single correct · +4 / −1
In case of isoelectronic species the size of F⁻, Ne and Na⁺is affected by :
- (a) Nuclear charge (z)
- (b) None of the factors because their size is the same
- (c) Electron-electron interaction in the outer orbitals
- (d) Principal quantum number (n)
Answer and solution
Answer (a) Nuclear charge (z)
Solution
Chemistry ma’am · 3 steps
Same 10 electrons, same shell; only the proton count changes, so the nuclear pull decides the size.
- What is common. F⁻, Ne and Na⁺ each have 10 electrons in the same arrangement, 1s² 2s² 2p⁶. So the outermost shell is n = 2 for all three.
Species Nuclear charge Z Electrons Outermost shell F⁻ 9 10 n = 2 Ne 10 10 n = 2 Na⁺ 11 10 n = 2 - What changes. Only the nuclear charge changes, from 9 to 11. With the same 10 electrons and the same shielding, more protons pull the electron cloud in harder, so the size shrinks as Z rises.
- So. The sizes follow F⁻ > Na⁺, and the factor that sets them is the nuclear charge (Z), option (a).
The idea to keep. For isoelectronic species, line them up by Z: more protons pulling on the same set of electrons means a smaller particle.
Answer from the NTA final answer key. Solution by PrepWiser.