JEE Main 2024 · 1 February · morning · Single correct · +4 / −1

In case of isoelectronic species the size of F⁻, Ne and Na⁺is affected by :

  1. (a) Nuclear charge (z)
  2. (b) None of the factors because their size is the same
  3. (c) Electron-electron interaction in the outer orbitals
  4. (d) Principal quantum number (n)
Answer and solution

Answer (a) Nuclear charge (z)

Solution

Chemistry ma’am · 3 steps

Same 10 electrons, same shell; only the proton count changes, so the nuclear pull decides the size.

  1. What is common. F⁻, Ne and Na⁺ each have 10 electrons in the same arrangement, 1s² 2s² 2p⁶. So the outermost shell is n = 2 for all three.
    SpeciesNuclear charge ZElectronsOutermost shell
    F⁻910n = 2
    Ne1010n = 2
    Na⁺1110n = 2
  2. What changes. Only the nuclear charge changes, from 9 to 11. With the same 10 electrons and the same shielding, more protons pull the electron cloud in harder, so the size shrinks as Z rises.
  3. So. The sizes follow F⁻ > Na⁺, and the factor that sets them is the nuclear charge (Z), option (a).

The idea to keep. For isoelectronic species, line them up by Z: more protons pulling on the same set of electrons means a smaller particle.

Answer from the NTA final answer key. Solution by PrepWiser.

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Asked about 120 times in JEE Main since 2020. This question is from 2024.