JEE Main 2022 · 28 July · evening · Single correct · +4 / −1

The correct decreasing order for metallic character is :

  1. (a) Na > Mg > Be > Si > P
  2. (b) P > Si > Be > Mg > Na
  3. (c) Si > P > Be > Na > Mg
  4. (d) Be > Na > Mg > Si > P
Answer and solution

Answer (a) Na > Mg > Be > Si > P

Solution

Chemistry ma’am · 4 steps

Metallic character is how easily an atom gives away electrons, so find where each one sits in the table.

  1. What it measures. Metallic character is the tendency to lose electrons and form positive ions. Low ionisation enthalpy and a large atom both make that easier.
  2. The two trends. Across a period, from left to right, metallic character decreases because nuclear charge grows and atoms shrink. Down a group it increases because the outer electron sits farther from the nucleus.
    ElementPeriod, groupNature
    Na3, group 1most metallic, loses 1 electron very easily
    Mg3, group 2metal, one place right of Na
    Be2, group 2metal, but small and less metallic than Mg (above it in group 2)
    Si3, group 14metalloid
    P3, group 15non-metal, least metallic
  3. Place Be. Be sits above Mg, so it is less metallic than Mg. It is still a true metal, so it ranks above the metalloid Si and the non-metal P.
  4. So. The decreasing order is Na > Mg > Be > Si > P, which is option (a).

The idea to keep. Metallic character rises as you go left and down the periodic table. Rank the metals first, then the metalloids, then the non-metals, and use the group trend to place elements from different periods.

Answer from the NTA final answer key. Solution by PrepWiser.

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Asked about 120 times in JEE Main since 2020. This question is from 2022.