JEE Main 2025 · 7 April · evening · Single correct · +4 / −1

Match List - I with List - II .
Choose the correct answer from the options given below :

List - IList - II
(A) Isothermal(I) ΔW (work done) = 0
(B) Adiabatic(II) ΔQ (supplied heat) = 0
(C) Isobaric(III) ΔU (change in internal energy) ≠ 0
(D) Isochoric(IV) ΔU = 0
  1. (a) (A)-(III), (B)-(II), (C)-(I), (D)-(IV)
  2. (b) (A)-(II), (B)-(IV), (C)-(I), (D)-(III)
  3. (c) (A)-(IV), (B)-(II), (C)-(III), (D)-(I)
  4. (d) (A)-(IV), (B)-(I), (C)-(III), (D)-(II)
Answer and solution

Answer (c) (A)-(IV), (B)-(II), (C)-(III), (D)-(I)

Solution

Physics sir · 2 steps

Ask what each process holds fixed, then see which quantity in Δ Q = Δ U + Δ W that kills.

  1. First law. Every match comes from Δ Q = Δ U + Δ W. For an ideal gas, Δ U depends only on temperature, and Δ W = P Δ V needs a volume change.
    ProcessWhat stays fixedConsequenceMatch
    (A) IsothermalTemperatureNo temperature change, so Δ U = 0(IV)
    (B) AdiabaticNo heat exchangeΔ Q = 0 by definition(II)
    (C) IsobaricPressureV changes at fixed P, so T changes and Δ U ≠ 0(III)
    (D) IsochoricVolumeΔ V = 0, so Δ W = 0(I)
  2. So. The matching is (A)-(IV), (B)-(II), (C)-(III), (D)-(I), which is option (c).

The idea to keep. Isothermal fixes T, so Δ U = 0. Adiabatic fixes heat, so Δ Q = 0. Isochoric fixes V, so Δ W = 0. Isobaric fixes none of these three, so here Δ U ≠ 0.

Answer from the NTA final answer key. Solution by PrepWiser.

Study Thermodynamics

Asked about 150 times in JEE Main since 2020. This question is from 2025.