JEE Main 2023 · 25 January · evening · Single correct · +4 / −1

Match List I with List II
Choose the correct answer from the options given below :

List IList II
A.Isothermal ProcessI.Work done by the gas decreases internal energy
B.Adiabatic ProcessII.No change in internal energy
C.Isochoric ProcessIII.The heat absorbed goes partly to increase internal energy and partly to do work
D.Isobaric ProcessIV.No work is done on or by the gas
  1. (a) A-I, B-II, C-IV, D-III
  2. (b) A-II, B-I, C-III, D-IV
  3. (c) A-II, B-I, C-IV, D-III
  4. (d) A-I, B-II, C-III, D-IV
Answer and solution

Answer (c) A-II, B-I, C-IV, D-III

Solution

Physics sir · 3 steps

Write Δ Q = Δ U + W, then ask which term each process forces to zero.

  1. First law. For any process on a gas, Δ Q = Δ U + W, where W is the work done by the gas. Each special process fixes one of these three terms, and that tells you its List II match.
    ProcessWhat is fixedFirst law becomesMatch
    A. IsothermalT constant, so Δ U = 0 for an ideal gasΔ Q = WII, no change in internal energy
    B. AdiabaticNo heat exchange, Δ Q = 0W = -Δ UI, work by the gas lowers U
    C. IsochoricV constant, so W = 0Δ Q = Δ UIV, no work on or by the gas
    D. IsobaricP constant, nothing is zeroΔ Q = Δ U + PΔ VIII, heat splits between U and work
  2. Why isobaric is III. At constant pressure the gas heats up, so Δ U > 0, and it expands, so W = PΔ V > 0. The heat absorbed pays for both.
  3. So. The matching is A-II, B-I, C-IV, D-III, which is option (c).

The idea to keep. Isothermal kills Δ U, adiabatic kills Δ Q, isochoric kills W. Isobaric kills nothing, so the heat is shared between Δ U and work.

Answer from the NTA final answer key. Solution by PrepWiser.

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Asked about 150 times in JEE Main since 2020. This question is from 2023.