JEE Main 2024 · 1 February · morning · Single correct · +4 / −1

Two moles a monoatomic gas is mixed with six moles of a diatomic gas. The molar specific heat of the mixture at constant volume is :

  1. (a) 3/2 R
  2. (b) 7/4 R
  3. (c) 5/2 R
  4. (d) 9/4 R
Answer and solution

Answer (d) 9/4 R

Solution

Physics sir · 3 steps

Add up the internal energy of both gases, then share it over all 8 moles: a mole-weighted average.

  1. Each gas alone. A monoatomic gas has 3 degrees of freedom, so C_V = 3/2R. A diatomic gas has 5, so C_V = 5/2R.
  2. Why average. Heating the mixture by Δ T at constant volume needs n₁ C_(V1)Δ T + n₂ C_(V2)Δ T. Divide this by the total moles n₁ + n₂ to get the heat per mole of mixture.

    C_V = (n₁ C_(V1) + n₂ C_(V2))/(n₁ + n₂) = (2 × 3/2R + 6 × 5/2R)/(2 + 6) = (3R + 15R)/8

  3. So. C_V = 18R/8 = 9/4R, which is option (d).

The idea to keep. For any gas mixture, the molar specific heat is the mole-weighted average of the individual values. Pair each C_V with its own number of moles.

Answer from the NTA final answer key. Solution by PrepWiser.

Study Kinetic Theory of Gases

Asked about 130 times in JEE Main since 2020. This question is from 2024.