JEE Main 2021 · 20 July · evening · Single correct · +4 / −1

The correct relation between the degrees of freedom f and the ratio of specific heat γ is :

  1. (a) f = 2/(γ - 1)
  2. (b) f = 2/(γ + 1)
  3. (c) f = (γ + 1)/2
  4. (d) f = 1/(γ + 1)
Answer and solution

Answer (a) f = 2/(γ - 1)

Solution

Physics sir · 3 steps

Write Cᵥ and Cₚ in terms of f, take their ratio, then turn the formula around to get f.

  1. Equipartition. Each degree of freedom carries 1/2RT per mole, so U = f/2RT and Cᵥ = f/2R. Mayer's relation gives Cₚ = Cᵥ + R = (f/2 + 1)R.

    γ = Cₚ/Cᵥ = (f/2+1)/(f/2) = 1 + 2/f

  2. Rearrange for f. Move the 1 across: γ - 1 = 2/f. Flip both sides to get f = 2/(γ - 1).
    OptionPut in γ = 5/3 (monatomic)Should give f = 3
    (a) 2/(γ - 1)2/(2/3) = 3matches
    (b) 2/(γ + 1)2/(8/3) = 3/4no
    (c) (γ + 1)/2(8/3)/2 = 4/3no
    (d) 1/(γ + 1)1/(8/3) = 3/8no
  3. So. The relation is f = 2/(γ - 1), which is option (a).

The idea to keep. Remember γ = 1 + 2/f. If you are unsure of a rearranged form, put in a monatomic gas, γ = 5/3 and f = 3, and check.

Answer from the NTA final answer key. Solution by PrepWiser.

Study Kinetic Theory of Gases

Asked about 130 times in JEE Main since 2020. This question is from 2021.