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Aldehydes & Ketones JEE Main PYQs, 2021 to 2026

Aldehydes & Ketones has 80 questions in JEE Main papers from 2020 to 2026, about 11 per year across all shifts. The free PDF has 11 of them, each with its answer and a step-by-step solution. The most asked topic is Preparation of Aldehydes and Ketones (41 questions), followed by Nucleophilic Addition Reactions (15) and Aldol Condensation (14).

Asked in JEE Main
802020–2026, all shifts
In this free PDF
11with answers + solutions
Asked in 2026
34Latest paper: 2026 Apr S2
Most asked topic
Preparation of Aldehydes and Ketones41 Qs · 51% of the chapter
Difficulty mix
36% easy · 64% mediumof the questions in the PDF

Answer key includedNo loginStep-by-step solutions

Source: official NTA JEE Main papers · Updated

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Aldehydes & Ketones questions per year

YearAskedIn PDF
2026345
2025132
202472
202361
202260
2021101
202040

in the free PDF asked, not in the PDFThe PDF only has questions we can print in full with a checked answer, so it holds 11 of the 80 asked.

Topic-wise weightage by year

How many Aldehydes & Ketones questions each topic had in every JEE Main year (all shifts), counting every question asked, including ones not in the PDF. Darker cells mean more questions.

TopicAskedShare2026202520242023202220212020
Preparation of Aldehydes and Ketones4151%322·1411
Nucleophilic Addition Reactions1519%·422·43
Aldol Condensation1418%252122·
Oxidation and Reduction911%·222·3·
Cannizzaro Reaction11%··1····
All topics80100%3413766104

Swipe the table sideways for older years.

Newest questions (2026)

All 5 JEE Main 2026 Aldehydes & Ketones questions in the free PDF, latest shift first. The 2026 papers asked 34 in all.

  1. JEE Main 2026 · 8 Apr · Shift 2 · Preparation of Aldehydes and Ketones

    ' xx ' is the product which is obtained from benzene by reacting it with carbon monoxide and hydrogen chloride in the presence of cuprous chloride. ' yy ' is the major product obtained from the benzene by reacting it with ethanoyl chloride in the presence of anhydrous AlCl3{\mathrm{AlCl}}_{3}. Product (major) obtained by heating xx and yy in the presence of alkali is zz. Total number of π\pi (pi) electrons in zz is ____\_\_\_\_ .

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  2. JEE Main 2026 · 6 Apr · Shift 2 · Preparation of Aldehydes and Ketones

    An optically active alkyl bromide C4H9Br{\mathrm{C}}_{4}{\mathrm{H}}_{9}{\mathrm{Br}}, reacts with ethanolic KOH to form major compound [A][{\mathrm{A}}] which reacts with bromine to give compound [B][{\mathrm{B}}]. Compound [B][{\mathrm{B}}] reacts with ethanolic KOH and sodamide to give compound [C]. One molecule of water adds to compound [C] on warming with mercuric sulphate and dilute sulphuric acid at 333 K to form compound [D]. The functional group in compound D will be confirmed by :

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  3. JEE Main 2026 · 6 Apr · Shift 1 · Preparation of Aldehydes and Ketones

    Given below are two statements :

    Statement I : 2, 6-diethylcyclohexanone and 6-methyl-2-n-propylcyclohexanone are metamers.

    Statement II : 2, 2, 6, 6 - tetramethylcyclohexanone exhibits keto-enol tautomerism.

    In the light of the above statements, choose the correct answer from the options given below

    Solve it with the step-by-step solution →
  4. JEE Main 2026 · 6 Apr · Shift 2 · Preparation of Aldehydes and Ketones

    ' xx ' is the product which is obtained by the hydrolysis of prop-1-yne in the presence of mercuric sulphate under dilute acidic medium at 333 K . ' yy ' is the product which is obtained by the reaction of ethane nitrile with methyl magnesium bromide in dry ether followed by hydrolysis. IUPAC name of product obtained from ' x′x^{{'}} and ' yy ' in the presence of barium hydroxide followed by heating is :

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  5. JEE Main 2026 · 24 Jan · Shift 2 · Preparation of Aldehydes and Ketones

    Grignard reagent RMgBr(P){\mathrm{RMgBr}}({\mathrm{P}}) reacts with water and forms a gas (Q)({\mathrm{Q}}). One gram of Q occupies 1.4dm31.4{\mathrm{dm}}^{3} at STP. (P) on reaction with dry ice in dry ether followed by H3O+{\mathrm{H}}_{3}{\mathrm{O}}^{{+}}forms a compound (Z). 0.1 mole of (Z) will weigh ____\_\_\_\_ g. (Nearest integer)

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Sample questions from recent papers

JEE Main 2025 · 3 Apr · Shift 1 · Oxidation and Reduction

Number of molecules from below which cannot give iodoform reaction is :

Ethanol, Isopropyl alcohol, Bromoacetone, 2-Butanol, 2-Butanone, Butanal, 2-Pentanone, 3-Pentanone, Pentanal and 3-Pentanol.

  1. (A)4
  2. (B)3
  3. (C)5
  4. (D)2
Show answerHide answer

Answer: (A)

Step-by-step solution

JEE Main 2024 · 9 Apr · Shift 2 · Nucleophilic Addition Reactions

Which of the following compounds will give silver mirror with ammoniacal silver nitrate?

A. Formic acid

B. Formaldehyde

C. Benzaldehyde

D. Acetone

Choose the correct answer from the options given below :

  1. (A)B and C only
  2. (B)C and D only
  3. (C)A, B and C only
  4. (D)A only
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Answer: (C)

Step-by-step solution

JEE Main 2024 · 4 Apr · Shift 1 · Aldol Condensation

Given below are two statements :

Statements I : Acidity of α\alpha-hydrogens of aldehydes and ketones is responsible for Aldol reaction.

Statement II : Reaction between benzaldehyde and ethanal will NOT give Cross - Aldol product.

In the light of the above statements, choose the most appropriate answer from the options given below :

  1. (A)Both Statement I and Statement II are incorrect
  2. (B)Statement I is correct but Statement II is incorrect
  3. (C)Both Statement I and Statement II are correct
  4. (D)Statement I is incorrect but Statement II is correct
Show answerHide answer

Answer: (B)

Step-by-step solution

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Frequently asked

How many questions come from Aldehydes & Ketones in JEE Main?

80 questions from 2020 to 2026, about 11 per year. In 2026 it had 34. The free PDF has 11 of them.

Which Aldehydes & Ketones topics are most important for JEE Main?

By past papers: Preparation of Aldehydes and Ketones (51%), Nucleophilic Addition Reactions (19%) and Aldol Condensation (18%) of all Aldehydes & Ketones questions.

Is the Aldehydes & Ketones PYQ PDF free?

Yes. The PDF, the answer key and every step-by-step solution on PrepWiser are free, with no login needed to practise.

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