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Chemical Bonding & Molecular Structure JEE Main PYQs, 2020 to 2025

Chemical Bonding & Molecular Structure has 89 questions in JEE Main papers from 2020 to 2025, about 15 per year across all shifts. The most asked topic is Molecular Orbital Theory (30 questions), followed by Dipole Moment (12) and Hydrogen Bonding (12).

Updated

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89Total PYQs
6Years covered
7Topics
2025 Apr S1Latest paper

Chemical Bonding & Molecular Structure questions per year

YearQuestions
20258
202429
202319
202215
20216
202012

Topic-wise weightage

TopicQuestionsShare of chapterLast asked
Molecular Orbital Theory3034%2025
Dipole Moment1214%2025
Hydrogen Bonding1213%2025
VSEPR Theory1213%2024
Hybridisation1011%2025
Ionic Bond78%2025
Covalent Bond and Lewis Structures67%2024

Sample questions from recent papers

JEE Main 2025 · 4 Apr · Shift 1 · Molecular Orbital Theory

Which of the following molecule(s) show/s paramagnetic behavior?

A. O2\mathrm{O}_2

B. N2\mathrm{N}_2

C. F2\mathrm{F}_2

D. S2\mathrm{S}_2

E. Cl2\mathrm{Cl}_2

Choose the correct answer from the options given below:

  1. (A) A & C only
  2. (B)A & E Only
  3. (C) A & D Only
  4. (D) B Only

Answer: (C)

Step-by-step solution

JEE Main 2025 · 3 Apr · Shift 2 · Hydrogen Bonding

Given below are two statements:

Statement I : Wet cotton clothes made of cellulose based carbohydrate takes comparatively longer time to get dried than wet nylon polymer based clothes.

Statement II : Intermolecular hydrogen bonding with water molecule is more in nylon-based clothes than in the case of cotton clothes.

In the light of above statements, choose the correct answer from the options given below

  1. (A)Both Statement I and Statement II are false
  2. (B)Both Statement I and Statement II are true
  3. (C)Statement I is false but Statement II is true
  4. (D)Statement I is true but Statement II is false

Answer: (D)

Step-by-step solution

JEE Main 2025 · 2 Apr · Shift 1 · Hybridisation

Among SO2,NF3,NH3,XeF2,ClF3\mathrm{SO}_2, \mathrm{NF}_3, \mathrm{NH}_3, \mathrm{XeF}_2, \mathrm{ClF}_3 and SF4\mathrm{SF}_4, the hybridization of the molecule with nonzero dipole moment and highest number of lone-pairs of electrons on the central atom is

  1. (A) sp3\mathrm{sp}^3
  2. (B) dsp2\mathrm{dsp}^2
  3. (C) sp3 d2\mathrm{sp}^3 \mathrm{~d}^2
  4. (D) sp3 d\mathrm{sp}^3 \mathrm{~d}

Answer: (D)

Step-by-step solution

JEE Main 2025 · 29 Jan · Shift 1 · Ionic Bond

An element ‘E’ has the ionisation enthalpy value of 374 kJ mol⁻¹. ‘E’ reacts with elements A, B, C and D with electron gain enthalpy values of −328, −349, −325 and −295 kJ mol⁻¹, respectively. The correct order of the products EA, EB, EC and ED in terms of ionic character is :

  1. (A)

    EB > EA > EC > ED

  2. (B)

    EA > EB > EC > ED

  3. (C)

    ED > EC > EA > EB

  4. (D)

    ED > EC > EB > EA

Answer: (A)

Step-by-step solution

JEE Main 2025 · 22 Jan · Shift 2 · Dipole Moment

Arrange the following compounds in increasing order of their dipole moment :

HBr,H2 S,NF3\mathrm{HBr}, \mathrm{H}_2 \mathrm{~S}, \mathrm{NF}_3 and CHCl3\mathrm{CHCl}_3

  1. (A)HBr<H2 S<NF3<CHCl3\mathrm{HBr}<\mathrm{H}_2 \mathrm{~S}<\mathrm{NF}_3<\mathrm{CHCl}_3
  2. (B)H2 S<HBr<NF3<CHCl3\mathrm{H}_2 \mathrm{~S}<\mathrm{HBr}<\mathrm{NF}_3<\mathrm{CHCl}_3
  3. (C)NF3<HBr<H2 S<CHCl3\mathrm{NF}_3<\mathrm{HBr}<\mathrm{H}_2 \mathrm{~S}<\mathrm{CHCl}_3
  4. (D)CHCl3<NF3<HBr<H2S\mathrm{CHCl}_3<\mathrm{NF}_3<\mathrm{HBr}<\mathrm{H}_2 \mathrm{S}

Answer: (C)

Step-by-step solution

JEE Main 2024 · 30 Jan · Shift 1 · VSEPR Theory

Aluminium chloride in acidified aqueous solution forms an ion having geometry

  1. (A)Square planar
  2. (B)Octahedral
  3. (C)Trigonal bipyramidal
  4. (D)Tetrahedral

Answer: (B)

Step-by-step solution

All 89 questions are in the free PDF above, grouped by topic.

Frequently asked

How many questions come from Chemical Bonding & Molecular Structure in JEE Main?

89 questions from 2020 to 2025, about 15 per year. In 2025 it had 8.

Which Chemical Bonding & Molecular Structure topics are most important for JEE Main?

By past papers: Molecular Orbital Theory (34%), Dipole Moment (14%) and Hydrogen Bonding (13%) of all Chemical Bonding & Molecular Structure questions.

Is the Chemical Bonding & Molecular Structure PYQ PDF free?

Yes. The PDF, the answer key and every step-by-step solution on PrepWiser are free, with no login needed to practise.

More Chemistry chapters

JEE Main PYQs by year: 2025 · 2024 · 2023 · 2022 · 2021 · 2020

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