Amines & Diazonium Salts JEE Main PYQs PDF, 2020–2026

Amines & Diazonium Salts questions per year

in the free PDF asked, not in the PDFThe PDF only has questions we can print in full with a checked answer, so it holds 154 of the 167 asked.

Topic-wise weightage by year

How many Amines & Diazonium Salts questions each topic had in every JEE Main year (all shifts), counting every question asked, including ones not in the PDF. Darker cells mean more questions.

Swipe the table sideways for older years.

Newest questions (2026)

The 12 newest of the 27 JEE Main 2026 Amines & Diazonium Salts questions in the free PDF, latest shift first.

1. JEE Main 2026 · 8 Apr · Shift 2 · Preparation of Amines

   Which statements are True?

   A. In Hoffmann bromamide degradation, 4 moles of NaOH and 2 moles of ${\mathrm{Br}}_{2}$ are consumed per mole of an amide

   B. Hoffmann bromamide reaction is not given by alkyl amides.

   C. Primary amines can be synthesized by Hoffmann bromamide degradation.

   D. Secondary amide on reaction with ${\mathrm{Br}}_{2}$ and NaOH will give secondary amine.

   E. The by-products of Hoffmann degradation are ${\mathrm{Na}}_{2}{\mathrm{CO}}_{3},{\mathrm{NaBr}}$ and ${\mathrm{H}}_{2}{\mathrm{O}}$.

   Choose the correct answer from the options given below :

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2. JEE Main 2026 · 6 Apr · Shift 1 · Diazonium Salts and Coupling

   $\text{ Consider the following sequence of reactions.}$

   

   The percentage of nitrogen in the yellow product $({\mathrm{X}})$ formed is $\_\_\_\_$ $\%$.

   (Nearest Integer)

   (Given Molar mass in ${\mathrm{g}}{\mathrm{mol}}^{{-1}}{\mathrm{H}}:1,{\mathrm{C}}:12,{\ \mathrm{N}}:14$ )

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3. JEE Main 2026 · 6 Apr · Shift 2 · Diazonium Salts and Coupling

   Consider the following organic reaction sequence. Choose the final product $(X)$ from the following (consider the major product in all intermediate reactions)

   
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4. JEE Main 2026 · 6 Apr · Shift 2 · Preparation of Amines

   The number of compounds from the following which can undergo reaction with ${\mathrm{Br}}_{2}/{\mathrm{KOH}}$ (alcoholic) to give respective products and these respective products can also be obtained separately by Gabriel phthalimide reaction is :

   
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5. JEE Main 2026 · 6 Apr · Shift 1 · Reactions of Amines

   Arrange the following compounds according to increasing order of boiling points.

   ${\mathrm{n}}-{\mathrm{C}}_{4}{\mathrm{H}}_{9}{\mathrm{OH}}({\ \mathrm{A}}),{\mathrm{n}}-{\mathrm{C}}_{4}{\mathrm{H}}_{9}{\mathrm{NH}}_{2}({\ \mathrm{B}}),{\mathrm{n}}-{\mathrm{C}}_{4}{\mathrm{H}}_{{10}}({\mathrm{C}})\text{ and}{\mathrm{C}}_{2}{\mathrm{H}}_{5}{\mathrm{NHC}}_{2}{\mathrm{H}}_{5}({\mathrm{D}}).$

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6. JEE Main 2026 · 5 Apr · Shift 1 · Diazonium Salts and Coupling

   $\text{Benzyl isocyanide can be obtained from}$

   

   Choose the correct answer from the options given below :

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7. JEE Main 2026 · 5 Apr · Shift 2 · Reactions of Amines

   Given below are two statements :

   Statement I : Heating benzamide with bromine in an ethanolic solution of sodium hydroxide will give benzylamine.

   Statement II : Nitration of aniline with ${\mathrm{HNO}}_{3}/{\mathrm{H}}_{2}{\mathrm{SO}}_{4}$ at 288 K produces $m$-nitroaniline in higher amount than $o$-nitroaniline ( pH adjusted).

   In the light of the above statements, choose the correct answer from the options given below :

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8. JEE Main 2026 · 5 Apr · Shift 1 · Preparation of Amines

   $\text{Identify the incorrect statements.}$

   

   Choose the correct answer from the options given below:

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9. JEE Main 2026 · 4 Apr · Shift 2 · Basicity of Amines

   $\text{ The strongest conjugate acid will result from:}$

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10. JEE Main 2026 · 4 Apr · Shift 1 · Diazonium Salts and Coupling

    Product C of the following reaction sequence will be

    
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11. JEE Main 2026 · 2 Apr · Shift 2 · Diazonium Salts and Coupling

    Identify compounds A and E in the following reaction sequence.
    
    

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12. JEE Main 2026 · 2 Apr · Shift 1 · Diazonium Salts and Coupling

    Consider the three aromatic molecules (P, Q and R) whose structures have been given below :

    

    The correct order regarding the reactivity of these compounds with ${\mathrm{Ph}}-\underset{(+)}{{\mathrm{N}}}\equiv {\ \mathrm{N}}{\mathrm{Cl}}^{{(-)}}$ under optimum but slightly acidic medium is :

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